First Preliminary Round

Dekedaha FC (Somalia)-0/7-Zamalek  
Venue: Borg Al-Arab Stadium, Alexandria, Egypt
Date: 16 Aug 2019
Scorers: Achraf Bencharki 5" Pen, 55" / Own Goal "Cano Molly Severin" 29" / Omar El-Said 45+1" / Mahmoud Hamdi "El-Wensh" 49" / Karim Bambo "Mohamed Said" 77" / Moustafa Mohamed 80"
Line-Up: Mohamed Awwad / Hamdi Nagguez / Mohamed Abdel Ghani / Mahmoud Hamdi "El-Wensh" / Mohamed Abdel Shafi / Mahmoud Abdel Razek "Shikabala" (Hazem Emam 72") / Youssef Ibrahim "Obama" (Karim Bambo "Mohamed Said" 59") / Mohamed Hassan / Mahmoud Abdel Aziz / Achraf Bencharki / Omar El-Said (Moustafa Mohamed 65")

Zamalek-6/0-Dekedaha FC (Somalia)  
Venue: Borg Al-Arab Stadium, Alexandria, Egypt
Date: 24 Aug 2019
Scorers: Moustafa Mohamed 25", 52" / Mahmoud Abdel Razek "Shikabala" 66", 73" / Mahmoud Alaa 78" Pen / Mahmoud Abdel Aziz 85"
Mahmoud Alaa missed a penalty in 77th min, the rebound resulted in another penalty which was also taken by him
Line-Up: Mohamed Abou Gabal / Hazem Emam / Mahmoud Alaa / Mohamed Abdel Ghani / Abdullah Gomaa / Mahmoud Abdel Razek "Shikabala" / Achraf Bencharki / Ferani Sassi / Mohamed Hassan (Mahmoud Abdel Aziz 38") / Karim Bambo "Mohamed Said" (Mohamed Abdel Shafi 46") / Moustafa Mohamed (Omar El-Said 69")

Second Preliminary Round (Round of 32)

AS Génération Foot (Senegal)-2/1-Zamalek  
Date: 14 Sep 2019
Scorers: Moustafa Mohamed 74"
Line-Up: Mohamed Abou Gabal / Hamdi Nagguez / Mahmoud Alaa / Mohamed Abdel Ghani / Mohamed Abdel Shafi / Mahmoud Hashem "Antar" (Khalid Boutaïb 46") / Youssef Ibrahim "Obama" / Ferjani Sassi / Tarek Hamed / Abdullah Gomaa (Ahmed Sayed "Zizo" 75") / Omar El-Said (Moustafa Mohamed 60")

Zamalek-1/0-AS Génération Foot (Senegal)  

Date: 29 Sep 2019
Scorer: Own Goal "Djibril Thialaw Diop" 19" 
Mahmoud Alaa missed a penalty for Zamalek in 65th min
Line-Up: Mohamed Awwad (Mohamed Sobhi 78") / Hamdi Nagguez (Hazem Emam 46") / Mahmoud Alaa / Mahmoud Hamdi "El-Wensh" / Abdullah Gomaa / Achraf Bencharki (Khalid Boutaïb 90+2") / Youssef Ibrahim "Obama" / Ferjani Sassi / Tarek Hamed / Ahmed Sayed "Zizo" / Moustafa Mohamed

 
Match was originally scheduled on September 29th but AS Génération Foot did not show in Borg Al Arab stadium in protest of CAF decision to postpone match from the 28th and Move it from Petrosport Stadium to Borg El-Arab Stadium. Later CAF decided to replay the match in Cairo on the 24th of October  
Line-Up in the cancelled match: Mohamed Awwad / Hamdi Nagguez / Mohamed Abdel Salam / Mahmoud Alaa / Abdullah Gomaa / Mahmoud Abdel Razek "Shikabala" / Tarek Hamed / Ferjani Sassi / Ahmed Sayed "Zizo" / Moustafa Mohamed / Khalid Boutaïb

First Round (Round of 16) - Group A

TP Mazembe (RD Congo)-3/0-Zamalek  
Date: 30 Nov 2019
Line-Up: Mohamed Awwad / Hamdi Nagguez / Mahmoud Alaa / Mahmoud Hamdi "El-Wensh" (Mohamed Abdel Ghani 21") / Abdullah Gomaa / Mohamed Ounajem (Mahmoud Abdel Razek "Shikabala" 76") / Achraf Bencharki / Hazem Emam (Mohamed Hassan 66") / Ferjani Sassi / Ahmed Sayed "Zizo" / Moustafa Mohamed

Zamalek-2/0-Primeiro de Agosto (Angola)
Date: 7 Dec 2019
Scorer: Achraf Bencharki 16", 68" 
Line-Up: Mohamed Awwad / Hazem Emam / Mahmoud Alaa / Mohamed Abdel Ghani / Abdullah Gomaa / Achraf Bencharki / Youssef Ibrahim "Obama" (Mohamed Ounajem 67") / Ferjani Sassi / Tarek Hamed / Ahmed Sayed "Zizo" (Mahmoud Abdel Razek "Shikabala" 85") / Moustafa Mohamed (Moustafa Fathi 81")

ZESCO United (Zambia)-1/1-Zamalek
Date: 28 Dec 2019
Scorer: Moustafa Mohamed 72" 
Line-Up: Mohamed Abou Gabal / Mohamed Abdel Ghani / Mahmoud Alaa / Mahmoud Hamdi "El-Wensh" / Mohamed Abdel Shafi / Mohamed Ounajem (Islam Gaber 81") / Youssef Ibrahim "Obama" / Ferjani Sassi / Tarek Hamed / Ahmed Sayed "Zizo" (Moustafa Mohamed 57") / Achraf Bencharki (Mohamed Abdel Salam 88")

Zamalek-2/0 ZESCO United (Zambia)
Date: 10 Jan 2020
Scorers: Achraf Bencharki 4" / Moustafa Mohamed 89" 
Line-Up: Mohamed Abou Gabal / Hazem Emam / Mahmoud Alaa / Mahmoud Hamdi "El-Wensh" / Mohamed Abdel Shafi / Mohamed Ounajem (Moustafa Fathi 76") / Youssef Ibrahim "Obama" (Ahmed Sayed "Zizo" 63") / Ferjani Sassi / Tarek Hamed / Achraf Bencharki (Islam Gaber 90+1") / Moustafa Mohamed

Zamalek-0/0-TP Mazembe (RD Congo)  
Date: 24 Jan 2020
Line-Up: Mohamed Abou Gabal / Hazem Emam / Mahmoud Alaa / Mahmoud Hamdi "El-Wensh" / Mohamed Abdel Shafi / Mahmoud Abdel Razek "Shikabala" (Mohamed Ounajem 61") / Youssef Ibrahim "Obama" (Moustafa Fathi 72") / Ferjani Sassi / Tarek Hamed / Ahmed Sayed "Zizo" / Moustafa Mohamed

Primeiro de Agosto (Angola)-0/0-Zamalek
Date: 1 Feb 2020
Line-Up: Mohamed Awwad / Ahmed Eid (Mahmoud Hamdi "El-Wensh" 71") / Mohamed Abdel Salam / Mohamed Abdel Ghani / Abdullah Gomaa / Moustafa Fathi (Kabongo Kasongo 64") / Islam Gaber / Mohamed Hassan / Ahmed Sayed "Zizo" / Karim Bambo "Mohamed Said" (Mohamed Hashem "Antar" 53") / Omar El-Said

Quarter Final

Zamalek-3/1-Espérance "Taragy" (Tunisia)  
Date: 28 Feb 2020
Zamalek Scorers: Mohamed Ounajem 31" / Achraf Bencharki 72" / Mahmoud Alaa 90+4" Pen
Espérance Scorer: Abdelraouf Benguit 27"
Line-Up: Mohamed Abou Gabal / Hazem Emam / Mahmoud Alaa / Mahmoud Hamdi "El-Wensh" / Mohamed Abdel Shafi / Mohamed Ounajem (Mahmoud Abdel Razek "Shikabala" 81") / Achraf Bencharki / Ferjani Sassi / Tarek Hamed / Ahmed Sayed "Zizo" (Abdullah Gomaa 83") / Moustafa Mohamed (Kabongo Kasongo 89")

Espérance "Taragy" (Tunisia)-1/0-Zamalek  
Date: 6 Mar 2020
Espérance Scorer: Billel Bensaha 5" Pen
Line-Up: Mohamed Abou Gabal / Hazem Emam / Mahmoud Alaa / Mahmoud Hamdi "El-Wensh" / Mohamed Abdel Shafi / Ahmed Sayed "Zizo" (Mohamed Abdel Salam 90+3") / Youssef Ibrahim "Obama" (Mohamed Hassan 88") / Ferjani Sassi / Tarek Hamed / Achraf Bencharki / Moustafa Mohamed (Kabongo Kasongo 81")

Semi Final

Rajaa "Raja Club Athletic RCA" (Morocco)-0/1-Zamalek  
Date: 18 Oct 2020
Zamalek Scorer: Achraf Bencharki 18"
Line-Up: Mohamed Abou Gabal / Ahmed Eid / Mohamed Abdel Ghani / Mahmoud Hamdi "El-Wensh" / Abdullah Gomaa / Tarek Hamed / Islam Gaber / Ahmed Sayed "Zizo" / Youssef Ibrahim "Obama" (Mohamed Ounajem 85") / Achraf Bencharki / Moustafa Mohamed

Zamalek-3/1  Rajaa "Raja Club Athletic RCA" (Morocco)
Date: 4 Nov 2020
Zamalek Scorer: Ferjani Sassi 61" / Moustafa Mohamed 85", 88"
Line-Up: Mohamed Abou Gabal / Ahmed Eid / Mahmoud Alaa / Mahmoud Hamdi "El-Wensh" / Abdullah Gomaa / Tarek Hamed (Mahmoud Abdel Razek "Shikabala" 90+3") / Islam Gaber / Ferjani Sassi / Ahmed Sayed "Zizo" / Achraf Bencharki / Moustafa Mohamed (Kabongo Kasongo 90+3")

Final

Zamalek-1/2-Ahly (Egypt)  
Date: 27 Nov 2020
Venue: Cairo Stadium
Referee: Mustapha Ghorbal (Algeria)
Zamalek Scorer: Mahmoud Abdel Razek "Shikabala" 31"
Ahly Scorers: Amr El-Sollayya 5" / Mohamed Magdi "Afsha" 86"

Zamalek Line-Up: Mohamed Abou Gabal / Ahmed Eid / Mohamed Abdel Ghani / Mahmoud Alaa / Islam Gaber (Omar El-Said 87") / Ferjani Sassi 90+3" / Tarek Hamed / Ahmed Sayed "Zizo" / Mahmoud Abdel Razek "Shikabala" (Kabongo Kasongo 55") / Achraf Bencharki / Moustafa Mohamed

Ahly Line-Up: Mohamed El-Shennawi 90+5" / Mohamed Hani 90+4" / Yasser Ibrahim / Ayman Ashraf / Ali Maaloul / Amr El-Sollayya 73" / Hamdi Fathi / Hussein El-Shahhat / Mohamed Magdi "Afsha" 86" (Rami Rabea 90+1") / Oluwafemi "Junior" Ajayi (Giraldo "Hermenegildo Bartolomeu" 67") / Marwan Mohsen (Mahmoud Abdel Monem "Kahraba" 90+2")